1 - yes you definitely can
2 - yes you can - but, I have read certain sources that say it should be from the same 24 hour period, so for example you shouldn't combine milk you pump on Monday with milk you pump on Wednesday. Also, if you are putting in the fridge, go by the earliest date when determining how long you can keep it (generally I've read it stays good for 5 to 7 days in the fridge, so go by the day of the first pumping session)